GCSE / IGCSE Chemistry – Chemical Changes and Energy
Reactivity series, acids and bases, electrolysis, energy changes.
This worksheet covers:
- This worksheet covers the reactivity series
- Acids and bases
- Electrolysis
- Energy changes
Use the relative atomic masses given in each question (rounded to whole numbers, as used at GCSE/IGCSE level); a calculator is allowed.
Questions
Place the following metals in order of reactivity, most reactive first: copper, magnesium, zinc, iron.
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Write the balanced symbol equation, including state symbols, for the reaction between magnesium and dilute hydrochloric acid.
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Define “neutralisation” and write the balanced symbol equation for the reaction between sodium hydroxide and sulfuric acid.
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Calculate the relative formula mass ($M_r$) of calcium carbonate, $\text{CaCO}_3$. ($A_r$: Ca $=40$, C $=12$, O $=16$)
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Explain, using ionic half-equations, what happens at each electrode during the electrolysis of molten lead(II) bromide, $\text{PbBr}_2$.
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Explain why aluminium is extracted by electrolysis rather than by reduction with carbon.
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In an experiment, $50\,\text{cm}^3$ of dilute hydrochloric acid at $20.0^{\circ}\text{C}$ was reacted with excess magnesium ribbon. The maximum temperature reached was $34.5^{\circ}\text{C}$. Calculate the temperature change, and state whether the reaction is exothermic or endothermic.
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Using the temperature change in the previous question, calculate the energy change in joules, given the specific heat capacity of the solution is $4.2\,\text{J/g}^{\circ}\text{C}$ and the mass of solution is $50\,\text{g}$.
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A student carries out an electrolysis experiment using a copper sulfate solution to electroplate a metal spoon with copper.(a) State which electrode, anode or cathode, the spoon should be, and explain why.(b) Write the half-equation for the reaction occurring at the copper anode used in electroplating.
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Using bond energies, calculate the overall enthalpy change for the reaction $\text{H}_2 + \text{Cl}_2 \rightarrow 2\text{HCl}$, given: bond energy H–H $=+436\,\text{kJ/mol}$, Cl–Cl $=+243\,\text{kJ/mol}$, H–Cl $=+432\,\text{kJ/mol}$.
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Calculate the percentage of aluminium by mass in aluminium oxide, $\text{Al}_2\text{O}_3$. ($A_r$: Al $=27$, O $=16$)
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A displacement reaction occurs when zinc granules are added to copper(II) sulfate solution.(a) Write the balanced symbol equation for this reaction.(b) Explain, in terms of electron transfer, why this is a redox reaction, identifying which species is oxidised and which is reduced.
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